Molecular approaches towards mixed metal oxides and their behaviour in mixed oxide support Au catalysts for CO oxidation

被引：25

作者：

Geserick, Jasmin ^{[1
]}

Froeschl, Thomas ^{[1
]}

Huesing, Nicola ^{[1
]}

Kucerova, Gabriela ^{[2
]}

Makosch, Martin ^{[2
]}

Diemant, Thomas ^{[2
]}

Eckle, Stephan ^{[2
]}

Behm, R. Juergen ^{[2
]}

机构：

[1] Univ Ulm, Inst Inorgan Chem 1, D-89069 Ulm, Germany

[2] Univ Ulm, Inst Catalysis & Surface Chem, D-89069 Ulm, Germany

来源：

DALTON TRANSACTIONS | 2011年 / 40卷 / 13期

关键词：

TEMPERATURE-PROGRAMMED DESORPTION; MESOPOROUS AU/TIO2 CATALYSTS; GOLD CATALYSTS; TITANIA-SILICA; CARBON-MONOXIDE; ACTIVE GOLD; MODIFIED SILANES; PARTICLE-SIZE; SURFACE-AREA; THIN-FILMS;

D O I：

10.1039/c0dt00911c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We herein report a water-based sol-gel approach towards porous mixed Si/Ti oxides using co-precipitated glycol-modified precursors. By adjusting synthesis parameters such as the pH value and the Si/Ti ratio of the precursor, the morphology as well as the Si/Ti-composition of the resulting mixed oxide particles can be varied in a wide range. The behaviour of the mixed oxides as substrates for Au catalysts and the performance of the resulting catalysts in the CO oxidation reaction was investigated and compared to catalysts supported on mesoporous anatase and rutile synthesized analogously. For comparable Au particle sizes and Au loadings, the composition of the mixed oxide support was found to significantly affect the reactivity and reaction behaviour, with mixed oxide supported Au catalysts synthesized at pH = 5 or 10 and with a Si/Ti-ratio of 1 : 19 and 1 : 34 exhibiting the maximum activity. In contrast to the enhanced activity, the mixed oxide supports do not lead to a significant improvement in deactivation behaviour and catalyst stability.

引用

页码：3269 / 3286

页数：18

共 101 条

[11] Adsorption of gases in multimolecular layers [J].

Brunauer, S ;

Emmett, PH ;

Teller, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :309-319

[12] Active and Stable Embedded Au@CeO2 Catalysts for Preferential Oxidation of CO [J].

Cargnello, Matteo ;

Gentilini, Cristina ;

Montini, Tiziano ;

Fonda, Emiliano ;

Mehraeen, Shareghe ;

Chi, Miaofang ;

Herrera-Collado, Miriam ;

Browning, Nigel D. ;

Polizzi, Stefano ;

Pasquato, Lucia ;

Fornasiero, Paolo .

CHEMISTRY OF MATERIALS, 2010, 22 (14) :4335-4345

[13]

Çelik Ö, 2001, ANGEW CHEM INT EDIT, V40, P3800

[14] Catalytically active gold on ordered titania supports [J].

Chen, Mingshu ;

Goodman, D. Wayne .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (09) :1860-1870

[15] Effect of molar ratio of TiO2/SiO2 on the properties of particles synthesized by flame spray pyrolysis [J].

Cho, Kuk ;

Chang, Hankwon ;

Park, Jin Ho ;

Kim, Byoung Gon ;

Jang, Hee Dong .

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2008, 14 (06) :860-863

[16] Titania-silica materials from the molecular precursor Ti[OSi(OtBu)3]4:: Selective epoxidation catalysts [J].

Coles, MP ;

Lugmair, CG ;

Terry, KW ;

Tilley, TD .

CHEMISTRY OF MATERIALS, 2000, 12 (01) :122-131

[17] Titania-silica: A model binary oxide catalyst system [J].

Davis, RJ ;

Liu, ZF .

CHEMISTRY OF MATERIALS, 1997, 9 (11) :2311-2324

[18] IR STUDY OF NO AND CO ADSORPTION ON A SILICA-SUPPORTED RU CATALYST [J].

DAVYDOV, AA ;

BELL, AT .

JOURNAL OF CATALYSIS, 1977, 49 (03) :332-344

[19] Mesoporous Au/TiO2 catalysts for low temperature CO oxidation [J].

Denkwitz, Y. ;

Geserick, J. ;

Hoermann, U. ;

Plzak, V. ;

Kaiser, U. ;

Husing, N. ;

Behm, R. J. .

CATALYSIS LETTERS, 2007, 119 (3-4) :199-208

[20] Stability and deactivation of unconditioned Au/Tio2 catalysts during CO oxidation in a near-stoichiometric and O2-rich reaction atmosphere [J].

Denkwitz, Y. ;

Zhao, Z. ;

Hoermann, U. ;

Kaiser, U. ;

Plzak, V. ;

Behm, R. J. .

JOURNAL OF CATALYSIS, 2007, 251 (02) :363-373

← 1 2 3 4 5 6 7 8 9 10 →