The one-dimensional coordination polymer poly[tetrakis[(4-chlorophenyl)methanaminium] [cadmate-μ-cyclohexaphosphorato]]

被引：10

作者：

Abid, Sonia ^{[1
]}

Al-Deyab, S. Salem ^{[2
]}

Rzaigui, Mohamed ^{[1
]}

机构：

[1] Fac Sci Bizerte, Lab Chim Mat, Zarzouna 7021, Tunisia

[2] King Saud Univ, Coll Sci, Petrochem Res Chair, Riyadh 11451, Saudi Arabia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

METAL-COMPLEXES; DERIVATIVES; ACIDS;

D O I：

10.1107/S160053681104133X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Cyclohexaphosphoric acid (P6O18H6) reacts with cadmium carbonate and 4-chlorobenzylamine (CBA) to give the mononuclear title complex, (C7H9ClN)(4)[Cd(P6O18)](n), in which the Cd-II atom, lying on an inversion centre, has an octahedral coordination built of six O atoms of two centrosymmetric P6O18 rings. Each P6O18 ligand acts as a bridge, linking two Cd-II atoms and forming an anionic coordination polymer [Cd(P6O18)(4-)](n) extending along [010]. Adjacent polymeric chains are connected through N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds, generating a three-dimensional supramolecular network.

引用

页码：M1549 / +

页数：13

共 16 条

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