Electronic structure and thermoelectric properties of Bi2Te3 crystals and graphene-doped Bi2Te3

被引:54
作者
Li, A. H. [1 ]
Shahbazi, M. [1 ]
Zhou, S. H. [1 ]
Wang, G. X. [1 ]
Zhang, C. [1 ]
Jood, P. [1 ]
Peleckis, G. [1 ]
Du, Y. [1 ]
Cheng, Z. X. [1 ]
Wang, X. L. [1 ]
Kuo, Y. K. [2 ]
机构
[1] Univ Wollongong, Inst Superconducting & Elect Mat, Wollongong, NSW 2522, Australia
[2] Natl Dong Hwa Univ, Dept Phys, Hualien 97401, Taiwan
基金
澳大利亚研究理事会;
关键词
Thermoelectric materials; Bi2Te3; Graphene; Seebeck coefficient; Conductivity; Density of states;
D O I
10.1016/j.tsf.2010.03.124
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The electronic structure and thermoelectric properties of Bi2Te3 single crystals and graphene-doped Bi2Te3 polycrystalline samples were investigated with the aid of first-principles calculations, X-ray diffraction, scanning electron microscopy, Rietveld refinement, and thermal and transport measurements. It was found that the p electrons from the Bi and Te atoms are responsible for the density of states near the Fermi level. Experimental results show that the graphene-doped Bi2Te3 exhibits lower thermal conductivity and has a higher figure-of-merit than the single crystals. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:E57 / E60
页数:4
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