Regioselective Oxyalkylation of Vinylarenes Catalyzed by Diatomite-Supported Manganese Oxide Nanoparticles

被引：62

作者：

Sun, Huayin

Zhang, Yonghui

Guo, Fengfeng

Zha, Zhenggen ^{[1
]}

Wang, Zhiyong

机构：

[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, CAS Key Lab Soft Matter Chem, Hefei 230026, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 77卷 / 07期

基金：

美国国家科学基金会;

关键词：

H BOND ACTIVATION; AEROBIC OXIDATION; MOLECULAR-OXYGEN; METAL-FREE; ALKENES; CARBOAMINATION; DIAMINATION; EFFICIENT; DIFUNCTIONALIZATION; ARYLATION;

D O I：

10.1021/jo2026367

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A regioselective oxyalkylation reaction of vinylarenes with cyclic ethers was developed under the catalysis of a new heterogeneous catalyst, the diatomite-supported Mn3O4 nanoparticles (SMONP-1). The use of this heterogeneous catalyst provided a novel approach for the synthesis of alpha-carbonyled beta-alkylated aryl derivatives via a sp(3) C-H bond functionalization under mild aerobic conditions.

引用

页码：3563 / 3569

页数：7

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