Metal organic frameworks for efficient catalytic conversion of CO2 and CO into applied products

被引:41
作者
Shah, Habib-Ur Rehman [1 ,2 ]
Ahmad, Khalil [1 ]
Bashir, Muhammad Sohail [3 ]
Shah, Syed Shoaib Ahmad [1 ,4 ]
Najam, Tayyaba [5 ]
Ashfaq, Muhammad [1 ]
机构
[1] Islamia Univ Bahawalpur, Inst Chem, Bahawalpur 63100, Punjab, Pakistan
[2] Univ Penn, Dept Chem, Roy & Diana Vagelos Labs, Philadelphia, PA 19104 USA
[3] Univ Sci & Technol China, Dept Polymer Sci & Engn, Hefei Natl Lab Phys Sci Microscale, CAS Key Lab Soft Matter Chem, Hefei 230026, Anhui, Peoples R China
[4] Univ Sci & Technol China, Dept Chem, Hefei Natl Lab Phys Sci Microscale, CAS Key Lab Soft Matter Chem, Hefei 230026, Anhui, Peoples R China
[5] Shenzhen Univ, Coll Chem & Environm Engn, Shenzhen 518060, Peoples R China
来源
MOLECULAR CATALYSIS | 2022年 / 517卷
关键词
Metal-organic frameworks; Catalysis; Composites; Carbon dioxide; Heterogeneous catalysis; Carbon monoxide; FISCHER-TROPSCH SYNTHESIS; CARBON-DIOXIDE; HETEROGENEOUS CATALYSTS; SELECTIVE CONVERSION; CONJUGATED POLYMERS; CUO/CEO2; CATALYSTS; COBALT CARBIDE; LOWER OLEFINS; ACTIVE-SITES; OXIDATION;
D O I
10.1016/j.mcat.2021.112055
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Catalytic conversion of toxic compounds into applied products is an emerging area of interest especially for the industrial as well as academic researchers. The development of catalysts for efficient conversion of carbon dioxide and carbon monoxide is highly desired for green world. Metal Organic Frameworks (MOFs) being porous and highly functionalized materials, appeared as an exceptional class of compounds due to their extraordinary and versatile catalytic properties. In this review, we have summarized recent advances in MOFs based materials for efficient heterogeneous catalytic conversion of CO2 and CO. Various catalysts such as Co, Fe, Au, Cu and Zn based MOFs have been successfully demonstrated not only for the conversion of CO2 and CO into applied products as well as for fisher-tropsch synthesis (FTS). This review also highlights about the epoxides cycloaddition corresponding to the various catalytic systems. In addition, this review offers the detailed discussion related to the new challenges and opportunities for effective transformation of CO2 and CO into useful products. We are hopeful that this review will provide the fundamental aspects to develop more efficient MOFS based catalysts for efficient removal of harmful pollutants.
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页数:15
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