The Mechanism of PEDOT: PSS Films with Organic Additives

被引:14
作者
Lien, Shui-Yang [1 ,2 ,3 ]
Lin, Po-Chen [4 ]
Chen, Wen-Ray [5 ]
Liu, Chuan-Hsi [6 ]
Lee, Kuan-Wei [7 ]
Wang, Na-Fu [8 ]
Huang, Chien-Jung [4 ]
机构
[1] Xiamen Univ Technol, Sch Optoelect & Commun Engn, Xiamen 361024, Peoples R China
[2] Da Yeh Univ, Dept Mat Sci & Engn, Dacun, Changhua 51591, Taiwan
[3] Xiamen Univ Technol, Fujian Key Lab Optoelect Technol & Devices, Xiamen 361024, Peoples R China
[4] Natl Univ Kaohsiung, Dept Appl Phys, Kaohsiung Univ Rd, Kaohsiung 81148, Taiwan
[5] Natl Formosa Univ, Dept Elect Engn, Wenhua Rd, Huwei 632301, Yunlin, Taiwan
[6] Natl Taiwan Normal Univ, Dept Mechatron Engn, Heping East Rd, Taipei 10610, Taiwan
[7] I Shou Univ, Dept Elect Engn, 1,Sec 1,Syuecheng Rd, Kaohsiung 84001, Taiwan
[8] Cheng Shiu Univ, Dept Elect Engn, Ctr Environm Toxin & Emerging Contaminant Res, Super Micro Mass Res & Technol Ctr, Chengcing Rd, Kaohsiung 82146, Taiwan
关键词
PEDOT; PSS; organic additive; bond-breaking reaction; phase separation; TRANSPORT; ACID;
D O I
10.3390/cryst12081109
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
This article demonstrates changes in the structures of poly (3,4-ethylene dioxythiophene): polystyrene sulfonate (PEDOT: PSS) with the addition of organic additives. The mechanisms of PEDOT: PSS are analyzed using X-ray photoelectron spectroscopy (XPS), cross-sectional images obtained from scanning electron microscopy (SEM), and contact angles. In this paper, a bond-breaking reaction and phase separation are successfully found to occur between PEDOT: PSS molecules and the organic additives. Our research also finds that this bond-breaking reaction and phase separation exist in the PEDOT: PSS-sorbitol-maltitol film at the same time. The addition of organic additives will improve the optical properties and the moisture stability of PEDOT: PSS films.
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页数:9
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共 33 条
  • [1] Overview for multimetallic nanostructures with biomedical, environmental and industrial applications
    Ahmed, Hanan B.
    Emam, Hossam E.
    [J]. JOURNAL OF MOLECULAR LIQUIDS, 2021, 321
  • [2] Manufacturing Organic Environmentally Friendly Electrical Circuits Using the Composites' Single-Walled Carbon Nanotubes and PEDOT:PSS
    Alamer, Fahad Alhashmi
    Badawi, Nujud M.
    [J]. ENERGY TECHNOLOGY, 2022, 10 (02)
  • [3] Dispersible composites of exfoliated graphite and polyaniline with improved electrochemical behaviour for solid-state chemical sensor applications
    Boeva, Zhanna A.
    Milakin, Konstantin A.
    Pesonen, Markus
    Ozerin, Aleksander N.
    Sergeyev, Vladimir G.
    Lindfors, Tom
    [J]. RSC ADVANCES, 2014, 4 (86): : 46340 - 46350
  • [4] Integrated Ionic-Additive Assisted Wet-Spinning of Highly Conductive and Stretchable PEDOT:PSS Fiber for Fibrous Organic Electrochemical Transistors
    Chen, Yanping
    Meng, Jie
    Xu, Yiman
    Li, Yaogang
    Zhang, Qinghong
    Hou, Chengyi
    Sun, Hengda
    Wang, Gang
    Wang, Hongzhi
    [J]. ADVANCED ELECTRONIC MATERIALS, 2021, 7 (08)
  • [5] PEDOT:PSS/graphene quantum dots films with enhanced thermoelectric properties via strong interfacial interaction and phase separation
    Du, Fei-Peng
    Cao, Nan-Nan
    Zhang, Yun-Fei
    Fu, Ping
    Wu, Yan-Guang
    Lin, Zhi-Dong
    Shi, Run
    Amini, Abbas
    Cheng, Chun
    [J]. SCIENTIFIC REPORTS, 2018, 8
  • [6] High transparent, low surface resistance ZTO/Ag/ZTO multilayer thin film electrodes on glass and polymer substrates
    Ekmekcioglu, Merve
    Erdogan, Nursev
    Astarlioglu, Aziz Taner
    Yigen, Serap
    Aygun, Gulnur
    Ozyuzer, Lutfi
    Ozdemir, Mehtap
    [J]. VACUUM, 2021, 187
  • [7] Phase Separation to Improve the Conductivity and Work Function of the PEDOT:PSS Solution for Silicon Hybrid Solar Cells
    Geng, Qi
    Wang, Zhe
    Gao, Zhongliang
    Gao, Ting
    Li, Yingfeng
    Chen, Lei
    Li, Meicheng
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2021, 125 (48) : 26379 - 26388
  • [8] Glycerol Phosphate Dimethacrylate: An Alternative Functional Phosphate Ester Monomer to 10-Methacryloyloxydecyl Dihydrogen Phosphate for Enamel Bonding
    Han, Fei
    Dai, Shiqi
    Yang, Jiaxue
    Shen, Jiadi
    Liao, Mengyuan
    Xie, Haifeng
    Chen, Chen
    [J]. ACS OMEGA, 2020, 5 (38): : 24826 - 24837
  • [9] The effects of solvents on the morphology and sheet resistance in poly (3,4-ethylenedioxythiophene)-polystyrenesulfonic acid (PEDOT-PSS) films
    Jönsson, SKM
    Birgerson, J
    Crispin, X
    Greczynski, G
    Osikowicz, W
    van der Gon, AWD
    Salaneck, WR
    Fahlman, M
    [J]. SYNTHETIC METALS, 2003, 139 (01) : 1 - 10
  • [10] Effect of Secondary Doping Using Sorbitol on Structure and Transport Properties of PEDOT-PSS Thin Films
    Khasim, Syed
    Pasha, Apsar
    Roy, Aashish S.
    Parveen, Ameena
    Badi, Nacer
    [J]. JOURNAL OF ELECTRONIC MATERIALS, 2017, 46 (07) : 4439 - 4447