Mild Organic Ammonium Tribromide-Mediated Regioselective Ring Opening of Epoxides with Alcohols, Water, Acetic Anhydride, and Amines Under Solvent-Free Reaction Conditions

被引：12
|
作者：
Singhal, Sweety [1 ]
Jain, Suman L. [1 ]
Sain, Bir [1 ]
机构：
[1] Indian Inst Petr, Council Sci & Ind Res, Div Chem Sci, Dehra Dun 248005, Uttar Pradesh, India
来源：
SYNTHETIC COMMUNICATIONS | 2011年 / 41卷 / 12期
关键词：
Metal free; MPHT; regioselective synthesis; ring opening; solid bromine; CARBONYL-COMPOUNDS; REUSABLE CATALYST; EFFICIENT; BROMINATION; PROTOCOL; ACID; OATB;
D O I：
10.1080/00397911.2010.493259
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[image omitted] Organic ammonium tribromide (OATB), N-methylpyrrolidine-2-one hydrotribromide (MPHT) was found to be an efficient catalyst for the regioselective ring opening of epoxides with various nucleophiles under solvent free conditions. This procedure occurs under neutral and mild reaction conditions with out adding any additive and afforded high yields of products.
引用
收藏
页码：1829 / 1837
页数：9
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