Synthesis and characterization of metastable Ag-B solid solutions

被引:0
作者
Zhang, J
Li, ZQ [1 ]
Sha, J
机构
[1] Zhejiang Univ, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
[2] Zhejiang Univ, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China
[3] Zhejiang Univ, Dept Phys, Hangzhou 310027, Peoples R China
关键词
mechanical alloying; Ag-B solid solution; metastable;
D O I
暂无
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Mechanical alloying (MA) was applied to Ag-B immiscible binary systems by ball milling elemental Ag and B powders. The microstructural characterization of the milled powders was carried out by XRD and TEM. The results show that face-centered-cubic (FCC) Ag-B solid solutions are formed and that the maximum ratio of B to Ag is 4 : 1. The structure evolution of Ag-B solid solution during ball milling indicates that the formation of Ag-B solid solution may be divided into two stages, which are mainly substitutional and interstitial solutions separately. The decomposition of the as-milled granules under the irradiation of electron beam is observed by TEM, which reveals that the solid solutions are metastable.
引用
收藏
页码:1066 / 1069
页数:4
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