Surface-Atom Core-Level Shift in GaAs(111)A-2x2

被引:10
作者
Pi, Tun-Wen [1 ]
Chen, Bor-Rong [2 ]
Huang, Mao-Lin [3 ]
Chiang, Tsung-Hung [2 ]
Wertheim, Gunther K. [4 ]
Hong, Minghwei [5 ,6 ]
Kwo, Jueinai [3 ,7 ]
机构
[1] Natl Synchrotron Radiat Res Ctr, Hsinchu 30076, Taiwan
[2] Natl Tsing Hua Univ, Dept Mat Sci & Engn, Hsinchu 30013, Taiwan
[3] Natl Tsing Hua Univ, Dept Phys, Hsinchu 30013, Taiwan
[4] Woodland Consulting, Morristown, NJ 07960 USA
[5] Natl Taiwan Univ, Grad Inst Appl Phys, Taipei 10617, Taiwan
[6] Natl Taiwan Univ, Dept Phys, Taipei 10617, Taiwan
[7] Natl Taiwan Univ, Ctr Condensed Matter Sci, Taipei 10617, Taiwan
关键词
GaAs; synchrotron radiation photoemission; surface core-level shift; RECONSTRUCTIONS; DIELECTRICS;
D O I
10.1143/JPSJ.81.064603
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Guided by the known reconstruction of the GaAs(111)A-2 x 2 surface, the Ga 3d electron surface atom core-level shifts was found to be 0.30 +/- 0.01 eV and that of the surface As atoms with three-fold Ga coordination -0.25 +/- 0.01 eV. The four-fold coordinated As surface atoms were not resolved from the bulk line. Measureable surface effects are confined to the outermost mixed Ga and As layer. The effective spin-orbit ratios are typically below the standard value of 2/3 at kinetic energies near threshold. This phenomenon is related to final state of the excited photo-electron. The inelastic mean-free path was found to average 4 angstrom with a minimum near a kinetic energy of 80 eV.
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页数:5
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