Cyclic polymers: Advances in their synthesis, properties, and biomedical applications

被引：80

作者：

Lienard, Romain ^{[1
,2
]}

De Winter, Julien ^{[2
]}

Coulembier, Olivier ^{[1
]}

机构：

[1] Univ Mons, Ctr Innovat & Res Mat & Polymers CIRMAP, Lab Polymer & Composite Mat LPCM, 23 Pl Parc, B-7000 Mons, Belgium

[2] Univ Mons, Interdisciplinary Ctr Mass Spectrometry CISMa, Organ Synth & Mass Spectrometry Lab S2MOs, Mons, Belgium

来源：

JOURNAL OF POLYMER SCIENCE | 2020年 / 58卷 / 11期

关键词：

cyclic polymer; macromolecular engineering; polymers; ring expansion; ring-closure; RING-OPENING-POLYMERIZATION; HIGH-MOLECULAR-WEIGHT; GLASS-TRANSITION TEMPERATURES; FRUSTRATED LEWIS PAIRS; EXPANSION METATHESIS POLYMERIZATION; CHAIN COMPETITION KINETICS; BLOCK-COPOLYMERS; DIBLOCK COPOLYMERS; CLICK-CHEMISTRY; EFFICIENT ROUTE;

D O I：

10.1002/pol.20200236

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Since the time first synthetic macrocycles were observed as academic curiosities, great advances have been made. Thanks to the development of controlled polymerization processes, new catalytic systems and characterization techniques during the last decades, well-defined cyclic polymers are now readily accessible. This further permits the determination of their unique set of properties, mainly due to their lack of chain ends, and their use for industrial applications can now be foreshadowed. This review aims to give an overview on the recent progresses in the field of ring polymers to this day. The current state of the art of the preparation of cyclic polymers, the challenges related to it such as the purification of the samples and the scalability of the synthetic processes, the properties arising from the cyclic topology and the potential use of cyclo-based polymers for biomedical applications are as many topics covered in this review.

引用

页码：1481 / 1502

页数：22

共 225 条

[31] Thermo-responsive drug delivery from polymeric micelles constructed using block copolymers of poly(N-isopropylacrylamide) and poly(butylmethacrylate) [J].