Is seven the minimum number of water molecules per ion pair for assured biological activity in ionic liquid-water mixtures?

被引：57

作者：

Ohno, Hiroyuki ^{[1
,2
,3
]}

Fujita, Kyoko ^{[1
,2
,3
]}

Kohno, Yuki ^{[1
,2
]}

机构：

[1] Tokyo Univ Agr & Technol, Dept Biotechnol, Koganei, Tokyo 1848588, Japan

[2] Tokyo Univ Agr & Technol, Grad Sch Engn, FILL, Koganei, Tokyo 1848588, Japan

[3] Japan Sci & Technol Agcy JST, CREST, Chiyoda Ku, Tokyo 1020076, Japan

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2015年 / 17卷 / 22期

基金：

日本学术振兴会;

关键词：

CYTOCHROME-C; COLD CRYSTALLIZATION; PHASE-CHANGE; ZWITTERIONS; STABILITY; PROTEINS; ACID;

D O I：

10.1039/c5cp00768b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ionic liquids (ILs) containing small amounts of water are called hydrated ILs and they show diverse physico-chemical properties that are strongly dependent on their water content. Some properties of hydrated ILs, such as biological activity and phase transition behaviour, were found to change non-linearly, with an inflection at a water molecule to ion pair ratio of around 7 : 1. This critical hydration number of ILs has been discussed in this paper with respect to the state of solvated water molecules.

引用

页码：14454 / 14460

页数：7

共 26 条

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