Asymmetric Organocatalytic Aziridination: Recent Advances

被引:28
|
作者
Roma, Elia [1 ]
Tosi, Eleonora [1 ]
Miceli, Martina [1 ]
Gasperi, Tecla [1 ]
机构
[1] Univ Roma Tre, Dept Sci, Sect Nanosci & Nanotechnol, Via Vasca Navale 79, I-00146 Rome, Italy
关键词
aziridines; heterocycles; amino acids; asymmetric catalysis; organocatalysis; electron-deficient compounds; RING-OPENING POLYMERIZATION; N-TOSYL AZIRIDINES; ENANTIOSELECTIVE SYNTHESIS; ALPHA; BETA-UNSATURATED ALDEHYDES; C-C; TERMINAL AZIRIDINES; DOMINO REACTIONS; MESO-AZIRIDINES; IMINES; CATALYSIS;
D O I
10.1002/ajoc.201800431
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Aziridines, the nitrogen counterparts of epoxides, are among the most challenging and intriguing heterocycles in organic chemistry, since they not only represent the endpoints of several total syntheses as common scaffolds in natural products, but also act as crucial precursors of complex molecules. The present review provides a brief overview of aziridine derivatives as well as the authors' choice of published papers that highlight recent enhancements concerning asymmetric organocatalytic strategies involved in aziridination reactions.
引用
收藏
页码:2357 / 2367
页数:11
相关论文
共 50 条
  • [31] Recent advances in organocatalytic enantioselective transfer hydrogenation
    Faisca Phillips, Ana Maria
    Pombeiro, Armando J. L.
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2017, 15 (11) : 2307 - 2340
  • [32] Recent advances and prospects in the organocatalytic synthesis of quinazolinones
    Borah, Biplob
    Swain, Sidhartha
    Patat, Mihir
    Chowhan, L. Raju
    FRONTIERS IN CHEMISTRY, 2022, 10
  • [33] Organocatalytic enantioselective aziridination of α,β-unsaturated aldehydes
    Vesely, Jan
    Ibrahem, Ismail
    Zhao, Gui-Ling
    Rios, Ramon
    Cordova, Armando
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (05) : 778 - 781
  • [34] Recent Applications of Asymmetric Organocatalytic Methods in Total Synthesis
    Parella, Ramarao
    Jakkampudi, Satish
    Zhao, John C. -G.
    CHEMISTRYSELECT, 2021, 6 (09): : 2252 - 2280
  • [35] Recent Advances in Organocatalytic Ring-opening Polymerization
    Ji, Mingjun
    Wu, Mengqi
    Han, Jiayu
    Zhang, Fanjun
    Peng, Hongwei
    Guo, Lihua
    CURRENT ORGANIC CHEMISTRY, 2021, 25 (02) : 272 - 286
  • [36] Recent advances towards organocatalytic enantioselective desymmetrizing reactions
    Xu, Yin
    Zhai, Tong-Yi
    Xu, Zhou
    Ye, Long-Wu
    TRENDS IN CHEMISTRY, 2022, 4 (03): : 191 - 205
  • [37] Recent advances in organocatalytic enantioselective syntheses of β-fluoroamine compounds
    Do, Taeyang
    Kim, Geun Ho
    Rios, Ramon
    Yang, Jung Woon
    MOLECULAR CATALYSIS, 2025, 576
  • [38] Recent Advances in Enantioselective Bronsted Base Organocatalytic Reactions
    Teng, Bo
    Lim, Wei Chun
    Tan, Choon-Hong
    SYNLETT, 2017, 28 (11) : 1272 - 1277
  • [39] Recent Advances in the Organocatalytic Enantioselective Synthesis of Functionalized -Lactones
    Mukherjee, Subrata
    Biju, Akkattu T.
    CHEMISTRY-AN ASIAN JOURNAL, 2018, 13 (17) : 2333 - 2349
  • [40] Recent Advances in Organocatalytic Asymmetric Morita-Baylis-Hillman/aza-Morita-Baylis-Hillman Reactions
    Wei, Yin
    Shi, Min
    CHEMICAL REVIEWS, 2013, 113 (08) : 6659 - 6690