Asymmetric Organocatalytic Aziridination: Recent Advances

被引：28

作者：

Roma, Elia ^{[1
]}

Tosi, Eleonora ^{[1
]}

Miceli, Martina ^{[1
]}

Gasperi, Tecla ^{[1
]}

机构：

[1] Univ Roma Tre, Dept Sci, Sect Nanosci & Nanotechnol, Via Vasca Navale 79, I-00146 Rome, Italy

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 7卷 / 12期

关键词：

aziridines; heterocycles; amino acids; asymmetric catalysis; organocatalysis; electron-deficient compounds; RING-OPENING POLYMERIZATION; N-TOSYL AZIRIDINES; ENANTIOSELECTIVE SYNTHESIS; ALPHA; BETA-UNSATURATED ALDEHYDES; C-C; TERMINAL AZIRIDINES; DOMINO REACTIONS; MESO-AZIRIDINES; IMINES; CATALYSIS;

D O I：

10.1002/ajoc.201800431

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aziridines, the nitrogen counterparts of epoxides, are among the most challenging and intriguing heterocycles in organic chemistry, since they not only represent the endpoints of several total syntheses as common scaffolds in natural products, but also act as crucial precursors of complex molecules. The present review provides a brief overview of aziridine derivatives as well as the authors' choice of published papers that highlight recent enhancements concerning asymmetric organocatalytic strategies involved in aziridination reactions.

引用

页码：2357 / 2367

页数：11

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