Synthesis of alpha-norbornenylpoly(ethylene oxide) macromonomers and their ring-opening metathesis polymerization

被引：123

作者：

Heroguez, V ^{[1
]}

Breunig, S ^{[1
]}

Gnanou, Y ^{[1
]}

Fontanille, M ^{[1
]}

机构：

[1] UNIV BORDEAUX 1,ENSCPB,UNITE MIXTE CNRS,LAB CHIM POLYMERES ORGAN,F-33402 TALENCE,FRANCE

来源：

MACROMOLECULES | 1996年 / 29卷 / 13期

关键词：

MACROMERS; REACTIVITY;

D O I：

10.1021/ma951797v

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This work focuses on the synthesis and the ring-opening metathesis polymerization of alpha-norbornenylpoly(ethylene oxide) macromonomers. Although obtained in 100% yield and with a narrow distribution of molar masses, the polymacromonomers exhibit degrees of polymerization that are systematically higher than expected. The reasons for this feature are thoroughly discussed.

引用

页码：4459 / 4464

页数：6

共 14 条

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