Are tetraalkylammonium cations inserted into palladium cathodes? Formation of new palladium phases involving tetraalkylammonium halides

被引：13

作者：

Cougnon, C ^{[1
]}

Simonet, J ^{[1
]}

机构：

[1] Univ Rennes 1, UMR CNRS 6510, Lab Electrochim Mol & Macromol, F-35042 Rennes, France

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2001年 / 507卷 / 1-2期

关键词：

palladium cathodes; tetraalkylammonium halides; insertion compounds; electrochemical corrosion;

D O I：

10.1016/S0022-0728(01)00431-4

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The cathodic behaviour of a wide variety of tetra alkylammonium halides was studied at a polished palladium cathode in aprotic dimethylformanaide. Coulometric and electrochemical quartz crystal microbalance analyses demonstrated the formation of clusters whose stoichiometry was determined, attesting to the reversible insertion of cations and anions belonging to the electrolyte into the metallic bulk. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：226 / 233

页数：8

共 21 条

[1] IRREVERSIBLE CATHODIC BEHAVIOR OF GRAPHITE IN THE PRESENCE OF SOME MIXTURES OF ONIUM SALTS [J].

BERNARD, G ;

SIMONET, J .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1979, 96 (02) :249-253

[2] TETRA-ALKYLAMMONIUM-GRAPHITE LAMELLAR COMPOUNDS - A NEW CLASS OF REDUCING REAGENTS IN ORGANIC-CHEMISTRY [J].

BERTHELOT, J ;

JUBAULT, M ;

SIMONET, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (13) :759-760

[3] POLYATOMIC ZINTL ANIONS OF THE POSTTRANSITION ELEMENTS [J].

CORBETT, JD .

CHEMICAL REVIEWS, 1985, 85 (05) :383-397

[4] Electrochemical reduction of tetraalkylammonium tetrafluoroborates at carbon cathodes in dimethylformamide [J].

Dahm, CE ;

Peters, DG .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1996, 402 (1-2) :91-96

[5]

Ghanimi A, 1997, NEW J CHEM, V21, P257

[6]

HALL EAH, 1979, J ELECTROANAL CHEM, V100, P197, DOI 10.1016/0368-1874(79)85112-6

[7] STUDIEN ZUM VORGANG DER WASSERSTOFFUBERTRAGUNG .12. HYDRIERENDE SPALTUNG VON SULFONEN MIT TETRAMETHYLAMMONIUM ALS ELEKTRONENUBERTRAGER [J].

HORNER, L ;

NEUMANN, H .

CHEMISCHE BERICHTE-RECUEIL, 1965, 98 (06) :1715-&

[8]

HORNER L, 1991, ORGANIC ELECTROCHEMI, pCH12

[9] TETRAALKYLAMMONIUM LEAD - ELECTROGENERATION AND STOICHIOMETRY [J].

KARIVMILLER, E ;

LAWIN, PB .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 247 (1-2) :345-349

[10] THE FIRST CATHODICALLY GENERATED TETRAALKYLAMMONIUM-TIN COMPOUNDS [J].

KARIVMILLER, E ;

CHRISTIAN, PD ;

SVETLICIC, V .

LANGMUIR, 1995, 11 (05) :1817-1821

← 1 2 3 →