Blue phosphors of dinuclear and mononuclear copper(I) and silver(I) complexes of 3,5-bis(trifluoromethyl)pyrazolate and the related bis(pyrazolyl)borate

被引：112

作者：

Omary, MA ^{[1
]}

Rawashdeh-Omary, MA

Diyabalanage, HVK

Dias, HVR

机构：

[1] Univ Texas, Dept Chem & Biochem, Arlington, TX 76019 USA

[2] Univ N Texas, Dept Chem, Denton, TX 76203 USA

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 26期

关键词：

D O I：

10.1021/ic0347586

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis, structure, and photoluminescence properties are described for the three-coordinate mononuclear and dinuclear complexes [H2B(3,5-(CF3)(2)PZ)(2)]M(2,4,6-collidine), M-1, and {[3,5-(CF3)(2)Pz]M(2,4,6-collidine)}(2), M-2, respectively (M = Cu; Ag). The solids exhibit bright blue phosphorescence, at room temperature for the copper compounds and at 77 K for all compounds. Ag-1, Cu-1, and Cu-2 exhibit blue pyrazole-based structured emissions with short phosphorescence lifetimes, 10(1)-10(2) mus, due to an internal heavy-metal effect. Meanwhile, Ag-2 exhibits curious multiple excitation-dependent emissions.

引用

页码：8612 / 8614

页数：3

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