Mechanical, thermal and flame retardant properties of magnesium hydroxide filled poly(vinyl chloride) composites: The effect of filler shape

被引：101

作者：

Lu, Yunhua ^{[1
]}

Wu, Chifei ^{[1
]}

Xu, Shiai ^{[1
,2
]}

机构：

[1] East China Univ Sci & Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Ultrafine Mat,Shanghai Key Lab Adv Polyme, Shanghai 200237, Peoples R China

[2] Qinghai Univ, Sch Chem Engn, Xining 810016, Qinghai, Peoples R China

来源：

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING | 2018年 / 113卷

基金：

中国国家自然科学基金;

关键词：

Magnesium hydroxide; Poly(vinyl chloride); Flame retardancy; Mechanical properties; IN-SITU POLYMERIZATION; PARTICLE-SIZE; PVC; BLENDS; NANOCOMPOSITES; DEGRADATION; STYRENE; MODEL;

D O I：

10.1016/j.compositesa.2018.07.012

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Magnesium hydroxide particle (MHP) and magnesium hydroxide whisker (MHW) were surface modified with a newly-synthesized polyether titanate coupling agent (eTi(4000)), and then incorporated into poly(vinyl chloride) (PVC) by melt blending to prepare PVC composites. The effect of filler shape on the mechanical, thermal and flame retardant properties of the resultant PVC composites was investigated. In general, MHP/PVC composites have better mechanical, thermal and flame retardant properties than MHW/PVC composites. The flexural modulus and impact strength of eTi(4000) modified MHP (eTi(4000)-MHP)/PVC composites are 5740 MPa and 8.3 kJ m(-2) at a 10 wt% filler loading, with an increase of 217% and 48.2% compared with that of MHP/PVC composites, respectively. Significantly, eTi(4000)-MHP/PVC composites show good flame retardancy, and the incorporation of 30 wt% of eTi(4000)-MHP results in 66.9% and 88.1% reduction of the total heat release and smoke production compared with that of pure PVC, respectively.

引用

页码：1 / 11

页数：11

共 42 条

[31] Structural and mechanistic aspects of the thermal degradation of poly(vinyl chloride) [J].