Progress on the Sulfonylation and Desulfonylative Reactions of Sulfonyl Chlorides

被引：14

作者：

Fu, Ying ^{[1
]}

Zhao, Xingling ^{[1
]}

Hou, Bo ^{[1
]}

机构：

[1] Northwest Normal Univ, Coll Chem & Chem Engn, Lanzhou 730070, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 36卷 / 06期

基金：

中国国家自然科学基金;

关键词：

sulfonyl chloride; cross-coupling reaction; desulfitative; CROSS-COUPLING REACTIONS; PALLADIUM-CATALYZED CYANATION; N-HETEROCYCLIC CARBENES; CARBON BOND FORMATION; ARENESULFONYL CHLORIDES; ARYL BROMIDES; ARYLSULFONYL CHLORIDES; SUZUKI-MIYAURA; ALKENESULFONYL CHLORIDES; RECYCLABLE CATALYSTS;

D O I：

10.6023/cjoc201512017

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Being an active class of electrophiles, the desulfitative cross-couplings of sulfonyl chlorides has emerged as a hot issue nowadays. Under suitable temperature and transitional metal catalysis, sulfonyl chlorides efficiently cross-coupled with a wide range of nucleophiles which were potential in several important organic synthesis. The transitional metal catalyzed desulfitative coupling reactions of sulfonyl chlorides are briefly reviewed and are compared with their corresponding sulfonylation reaction in order to find the key factors that determine desulfonation and further providing reliable proposal for future researches.

引用

页码：1184 / 1196

页数：13

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