Applications of laser-induced breakdown spectroscopy in cultural heritage and archaeology: a critical review

被引：135

作者：

Botto, Asia ^{[1
]}

Campanella, Beatrice ^{[2
]}

Legnaioli, Stefano ^{[2
]}

Lezzerini, Marco ^{[3
]}

Lorenzetti, Giulia ^{[2
]}

Pagnotta, Stefano ^{[2
,3
]}

Poggialini, Francesco ^{[2
,4
]}

Palleschi, Vincenzo ^{[2
]}

机构：

[1] Univ Pisa, Dept Chem & Ind Chem, Via G Moruzzi 13, I-56124 Pisa, Italy

[2] CNR, Res Area, Appl & Laser Spect Lab, Inst Chem Organometall Cpds, Via G Moruzzi 1, I-56124 Pisa, Italy

[3] Univ Pisa, Dept Earth Sci, Via Santa Maria 53, I-56126 Pisa, Italy

[4] Scuola Normale Super Pisa, Piazza Cavalieri 7, I-56126 Pisa, Italy

来源：

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY | 2019年 / 34卷 / 01期

关键词：

X-RAY-FLUORESCENCE; DUAL PULSE EXCITATION; COPPER-BASED-ALLOYS; ELEMENTAL ANALYSIS; INDUCED PLASMA; PAINTED ARTWORKS; WALL PAINTINGS; IN-SITU; COMPOSITIONAL ANALYSIS; QUANTITATIVE-ANALYSIS;

D O I：

10.1039/c8ja00319j

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

In this paper, we present a critical review on the applications of the Laser-Induced Breakdown Spectroscopy (LIBS) technique in cultural heritage and archaeology. The strategies used by the groups involved in this kind of research for the analysis of the typical materials of interest (metals, pigments, pottery, glass, etc.) are discussed in detail, as well as the use of LIBS in combination with other techniques (LIBS and Raman, LIBS and XRF, and LIBS and MS). Specific applications of LIBS as a support for cultural heritage restoration and the application of the technique for the analysis of underwater objects are presented in separate sessions. In conclusion, new trends of LIBS for cultural heritage and archaeology (micro-LIBS analysis, 3D elemental imaging, and surface- and nanoparticle-enhanced LIBS) are introduced and discussed.

引用

页码：81 / 103

页数：23

共 210 条

[1] Estimation of calcified tissues hardness via calcium and magnesium ionic to atomic line intensity ratio in laser induced breakdown spectra [J].