Volumetric behavior of decane plus carbon dioxide at high pressures.: Measurement and calculation

被引：45

作者：

Bessières, D ^{[1
]}

Saint-Guirons, H ^{[1
]}

Daridon, JL ^{[1
]}

机构：

[1] Lab Fluides Complexes, F-64013 Pau, France

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2001年 / 46卷 / 05期

关键词：

D O I：

10.1021/je010016k

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The volumetric behavior of carbon dioxide (1) + decane (2) mixtures has been investigated under the high pressures 20, 30, and 40 MPa in the temperature range [308.15 K to 368.15 K]. Densities have been measured for pure decane and for x(1) = 0.15, 0.30, 0.51, 0.66, 0.78, and 0.84. Density variations show a peculiar behavior: a crossover phenomenon with the composition at a given pressure and temperature is observed. The measured fluid densities have been compared with values predicted by equations of state with various mixing rules. This comparative study has revealed models well adapted to these density estimations.

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页码：1136 / 1139

页数：4

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