Cu2-cluster-based MOF with open metal sites and Lewis basic sites: Construction, CO2 adsorption and fixation

被引：11

作者：

Liu, Yong-Liang ^{[1
]}

Zhao, Yuxi ^{[1
]}

Zhang, Jiahao ^{[1
]}

Ye, Ye ^{[1
]}

Sun, Qianqian ^{[1
]}

机构：

[1] Shang Luo Univ, Coll Chem Engn & Modern Mat, Shaanxi Engn Res Ctr Mineral Resources Clean & Ef, Shaanxi Key Lab Comprehens Utilizat Tailings Reso, Shang Luo 726000, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2022年 / 313卷

关键词：

ORGANIC FRAMEWORK; PHOTOCATALYTIC REDUCTION; CATALYTIC CONVERSION; CYCLIC CARBONATES; CYCLOADDITION; EFFICIENT; EPOXIDES; CAPTURE; SELECTIVITY; ARGON;

D O I：

10.1016/j.jssc.2022.123332

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new Cu-2 cluster based MOF, namely, [Cu-2(dcpn) (H2O) (OH)]center dot 0.5DMF center dot 0.5H(2)O (1) has been successfully constructed from Cu(II) ion and 5-(2',5'-dicarboxylphenyl) nicotic acid. The 1 exhibits high porosity, and water stability in pH = 0 -13 aqueous solutions. Taking advantage of synergetic effect of the high density of Lewis acid Cu(II) and Lewis base -OH, the activated 1a possesses a certain CO2 uptake capacity. More importantly, 1a has an efficient catalytic activity and recyclability toward CO2 cycloaddition with epoxides under relatively mild conditions.

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页数：6

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