The first structure of a Cerium(IV) phosphate:: Ab initio Rietveld analysis of CeIV(PO4)(HPO4)0.5(H2O)0.5

被引：34

作者：

Nazaraly, M ^{[1
]}

Wallez, G ^{[1
]}

Chanéac, C ^{[1
]}

Tronc, E ^{[1
]}

Ribot, F ^{[1
]}

Quarton, M ^{[1
]}

Jolivet, JP ^{[1
]}

机构：

[1] Univ Paris 06, UMR 7574, CNRS, F-75252 Paris, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 35期

关键词：

cerium; layered compounds; NMR spectroscopy; phosphates; structure elucidation;

D O I：

10.1002/anie.200501871

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Layer apparent: Crystalline cerium(IV) phosphates have been studied for a long time as ion exchangers, but their structures have remained unknown. The structure of a cerium(IV) phosphate has been determined (see picture: tetrahedra PO4, yellow Ce, blue O (water)) and clearly explains a notable feature of this compound, its inability to intercalate amines. The X-ray study is supported by solid-state NMR spectroscopy investigations. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

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收藏

页码：5691 / 5694

页数：4

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