The first structure of a Cerium(IV) phosphate:: Ab initio Rietveld analysis of CeIV(PO4)(HPO4)0.5(H2O)0.5

被引：33
|
作者：
Nazaraly, M [1 ]
Wallez, G [1 ]
Chanéac, C [1 ]
Tronc, E [1 ]
Ribot, F [1 ]
Quarton, M [1 ]
Jolivet, JP [1 ]
机构：
[1] Univ Paris 06, UMR 7574, CNRS, F-75252 Paris, France
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 35期
关键词：
cerium; layered compounds; NMR spectroscopy; phosphates; structure elucidation;
D O I：
10.1002/anie.200501871
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Layer apparent: Crystalline cerium(IV) phosphates have been studied for a long time as ion exchangers, but their structures have remained unknown. The structure of a cerium(IV) phosphate has been determined (see picture: tetrahedra PO4, yellow Ce, blue O (water)) and clearly explains a notable feature of this compound, its inability to intercalate amines. The X-ray study is supported by solid-state NMR spectroscopy investigations. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：5691 / 5694
页数：4
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