Interaction of thorium(IV) with nitrate in aqueous solution: medium effect or weak complexation?

被引：10

作者：

Di Bernardo, Plinio ^{[1
]}

Zanonato, Pierluigi ^{[1
]}

Rao, Linfeng ^{[2
]}

Bismondo, Arturo ^{[3
]}

Endrizzi, Francesco ^{[1
]}

机构：

[1] Univ Padua, Dipartimento Sci Chim, I-35131 Padua, Italy

[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Berkeley, CA 94720 USA

[3] CNR, Ist Chim Inorgan & Superfici, I-35127 Padua, Italy

来源：

DALTON TRANSACTIONS | 2011年 / 40卷 / 36期

关键词：

TRIVALENT LANTHANIDE; SOLVENT-EXTRACTION; FUEL-CYCLE; URANIUM(VI); ACETATE; THERMODYNAMICS; POWER; ION;

D O I：

10.1039/c1dt10325c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Microcalorimetric titrations were performed to study the Th(IV)/nitrate interaction in aqueous solution. The results show the formation of a weak mononuclear complex of Th(IV) with nitrate and allow the determination of the complexation thermodynamic parameters at 298 K and ionic strength 1.0 mol dm(-3). The reaction is endothermic and entropy driven. Data and comparison with similar actinide(IV) complexes allow to confirm the inner-sphere nature of the Th(NO3)(3+) complex.

引用

页码：9101 / 9105

页数：5

共 50 条

[1] Complexation of some trivalent lanthanides, scandium(III) and thorium(IV) by benzylidenepyruvates in aqueous solution
Marques, R.N.
Melios, C.B.
Pereira, N.C.S.
Siqueira, O.S.
de Moraes, M.
Molina, M.
Ionashiro, M.
Journal of Alloys and Compounds, 1997, 249 (1 -2 pt 1): : 102 - 105
[2] Complexation of some trivalent lanthanides, scandium(III) and thorium(IV) by benzylidenepyruvates in aqueous solution
Marques, RN
Melios, CB
Pereira, NCS
Siqueira, OS
deMoraes, M
Molina, M
JOURNAL OF ALLOYS AND COMPOUNDS, 1997, 249 (1-2) : 102 - 105
[3] Complexation of some trivalent lanthanides, scandium(III) and thorium(IV) by benzylidenepyruvates and cinnamylidenepyruvate in aqueous solution
1600, Elsevier Science S.A., Lausanne, Switzerland (225):
[4] Complexation and interaction modelling in a thorium (IV)-mycobacterial siderophore system
MacCordick, H. J.
Wendling, O.
Antony, M.-S.
Cell Motility and the Cytoskeleton, 30 (03):
[5] Complexation of thorium(IV) with 2-furoic acid and 2-thenoic acid in aqueous solution
Bismondo, A
Di Bernardo, P
Zanonato, PL
Jiang, J
Rao, LF
DALTON TRANSACTIONS, 2003, (03) : 469 - 474
[6] COMPLEXATION OF SOME TRIVALENT LANTHANIDES, SCANDIUM(III) AND THORIUM(IV) BY BENZYLIDENEPYRUVATES AND CINNAMYLIDENEPYRUVATE IN AQUEOUS-SOLUTION
SIQUEIRA, OS
MELIOS, CB
IONASHIRO, M
DEMORAES, M
MOLINA, M
JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 225 (1-2) : 267 - 270
[7] HYDROLYSIS OF THE THORIUM(IV) ION IN SODIUM-NITRATE MEDIUM
MILIC, NB
SURANJI, TM
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1982, 60 (11): : 1298 - 1303
[8] Hydration and Hydrolysis of Thorium(IV) in Aqueous Solution and the Structures of Two Crystalline Thorium(IV) Hydrates
Torapava, Natallia
Persson, Ingmar
Eriksson, Lars
Lundberg, Daniel
INORGANIC CHEMISTRY, 2009, 48 (24) : 11712 - 11723
[9] COMPLEXATION AND INTERACTION MODELING IN A THORIUM(IV) MYCOBACTERIAL-SIDEROPHORE SYSTEM
MACCORDICK, HJ
WENDLING, O
ANTONY, MS
CURRENT SCIENCE, 1995, 68 (08): : 834 - 836
[10] Aqueous Complexation of Thorium(IV), Uranium(IV), Neptunium(IV), Plutonium(III/IV), and Cerium(III/IV) with DTPA
Brown, M. Alex
Paulenova, Alena
Gelis, Artem V.
INORGANIC CHEMISTRY, 2012, 51 (14) : 7741 - 7748

← 1 2 3 4 5 →