Corrosion behaviour of AZ91D and AM50 magnesium alloys with Nd and Gd additions in humid environments

被引:116
作者
Arrabal, R. [1 ]
Matykina, E. [1 ]
Pardo, A. [1 ]
Merino, M. C. [1 ]
Paucar, K. [2 ]
Mohedano, M. [1 ]
Casajus, P. [1 ]
机构
[1] Univ Complutense Madrid, Fac Ciencias Quim, Dept Ciencia Mat, E-28040 Madrid, Spain
[2] Univ Nacl Ingn, Fac Ingn Quim & Text, Lima, Peru
关键词
Magnesium; Rare earth elements; Weight loss; Atmospheric corrosion; ATMOSPHERIC CORROSION; MECHANICAL-PROPERTIES; WATER-VAPOR; MICROSTRUCTURE; RESISTANCE; NEODYMIUM; ALUMINUM; XPS;
D O I
10.1016/j.corsci.2011.10.038
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
AM50 and AZ91D alloys modified with rare earths (RE) were evaluated under atmospheric conditions. Nd and Gd additions resulted in formation of Al2RE and Al-Mn-RE compounds and reduction of the fraction of beta-phase. According to surface potential maps, RE-containing intermetallics were more noble than the beta-phase, but less than Al-Mn inclusions. As a result, the action of micro-galvanic couples depended on the added amount of RE and the initial alloy microstructure. Nd or Gd additions improved the corrosion resistance of the AM50 alloy by up to 43%, but had no significant effect on the corrosion resistance of the AZ91D alloy. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:351 / 362
页数:12
相关论文
共 33 条
[1]   Evaluation of microstructural effects on corrosion behaviour of AZ91D magnesium alloy [J].
Ambat, R ;
Aung, NN ;
Zhou, W .
CORROSION SCIENCE, 2000, 42 (08) :1433-1455
[2]   Effect of Nd on the corrosion behaviour of AM50 and AZ91D magnesium alloys in 3.5 wt.% NaCl solution [J].
Arrabal, R. ;
Pardo, A. ;
Merino, M. C. ;
Mohedano, M. ;
Casajus, P. ;
Paucar, K. ;
Garces, G. .
CORROSION SCIENCE, 2012, 55 :301-312
[3]   Corrosion behaviour of Mg/Al alloys in high humidity atmospheres [J].
Arrabal, R. ;
Pardo, A. ;
Merino, M. C. ;
Merino, S. ;
Mohedano, M. ;
Casajus, P. .
MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION, 2011, 62 (04) :326-334
[4]  
Arrabal R., CORROSION IN PRESS
[5]   Influence of cerium on the microstructure, mechanical properties and corrosion resistance of magnesium alloy [J].
Fan, Yu ;
Wu, Guohua ;
Zhai, Chunquan .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2006, 433 (1-2) :208-215
[6]   XPS study of the effect of aluminium on the atmospheric corrosion of the AZ31 magnesium alloy [J].
Feliu, S., Jr. ;
Merino, M. C. ;
Arrabal, R. ;
Coy, A. E. ;
Matykina, E. .
SURFACE AND INTERFACE ANALYSIS, 2009, 41 (03) :143-150
[7]   Correlation between the surface chemistry and the atmospheric corrosion of AZ31, AZ80 and AZ91D magnesium alloys [J].
Feliu, S., Jr. ;
Pardo, A. ;
Merino, M. C. ;
Coy, A. E. ;
Viejo, F. ;
Arrabal, R. .
APPLIED SURFACE SCIENCE, 2009, 255 (07) :4102-4108
[8]   Atmospheric corrosion of magnesium alloys AZ31 and AZ61 under continuous condensation conditions [J].
Feliu, Sebastian, Jr. ;
Maffiotte, C. ;
Carlos Galvan, Juan ;
Barranco, Violeta .
CORROSION SCIENCE, 2011, 53 (05) :1865-1872
[9]   Atmospheric corrosion of field-exposed magnesium alloy AZ91D [J].
Jonsson, Martin ;
Persson, Dan ;
Leygraf, Christofer .
CORROSION SCIENCE, 2008, 50 (05) :1406-1413
[10]   Corrosion product formation during NaCl induced atmospheric corrosion of magnesium alloy AZ91D [J].
Jonsson, Martin ;
Persson, Dan ;
Thierry, Dominique .
CORROSION SCIENCE, 2007, 49 (03) :1540-1558