Coordination polymers of scandium sulfate.: Crystal structures of (H2Bipy)[Sc(H2O)(SO4)2]2 . 2H2O and (H2Bipy)[HSO4]2

被引：7

作者：

Petrosyants, SP

Ilyukhin, AB

Sukhorukov, AY

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

[2] Russian Acad Sci, Higher Chem Coll, Moscow, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2005年 / 31卷 / 08期

基金：

俄罗斯基础研究基金会;

关键词：

Polymer; Sulfate; 2H2O; Crystal Structure; Inorganic Chemistry;

D O I：

10.1007/s11173-005-0134-y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Compounds with the general formula Cat(x)[Sc(H2O)(z)(SO4)(y)] - nH(2)O (Cat = NH4, H(2)Bipy (Bipy is 4,4'-bipyridine), and HEdp (Edp is ethylenedipyridine) are synthesized and identified by elemental analysis and IR spectral data. The X-ray diffraction analysis of (H(2)Bipy)[Sc(H2O)(SO4)(2)](2) center dot 2H(2)O shows that in the structure of this compound, the chains of ScO6 octahedra and SO4 tetrahedra are united to form ribbons due to the tridentate coordination of the sulfate ion. The ribbons form a framework, whose infinite cavities contain H(2)Bipy(2+) cations.

引用

页码：545 / 551

页数：7

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