Lighting up carbon monoxide in living cells by a readily available and highly sensitive colorimetric and fluorescent probe

被引：68

作者：

Feng, Weiyong ^{[1
]}

Liu, Dandan ^{[1
]}

Zhai, Qisong ^{[1
]}

Feng, Guoqiang ^{[1
]}

机构：

[1] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, 152 Luoyu Rd, Wuhan 430079, Peoples R China

来源：

SENSORS AND ACTUATORS B-CHEMICAL | 2017年 / 240卷

基金：

中国国家自然科学基金;

关键词：

Carbon monoxide; Fluorescent probe; Tsuji-Trost reaction; Living cells; CARBENE COORDINATION CHEMISTRY; BINUCLEAR RHODIUM COMPLEXES; PD(0) MEDIATED REACTION; TURN-ON PROBE; SELECTIVE DETECTION; FLUOROGENIC PROBES; CO; PALLADIUM; LIGAND; 1,10-PHENANTHROLINE;

D O I：

10.1016/j.snb.2016.09.023

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Carbon monoxide (CO) is an important gasotransmitter in living systems. The biological detection of this gasotransmitter is still in its infancy and urgently needs probes. In this paper, a novel fluorescent probe system, which is based on the Pd-0-mediated Tsuji-Trost reaction, is reported for rapid detection of CO both in in vitro and in living cells. This probe system is readily available and shows excellent sensing properties for CO including rapid and distinct colorimetric and fluorescent turn-on responses, high selectivity and sensitivity with a low detection limit (25 nM) in aqueous solution under mild conditions. In addition, fluorescent imaging of CO in living cells can be conveniently achieved by a low dose of this probe system. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：625 / 630

页数：6

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