Transition metal-catalyzed cross-coupling reactions of unactivated aliphatic C-X bonds

被引：0

作者：

Luh, TY ^{[1
]}

机构：

[1] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI 106,TAIWAN

来源：

REVIEWS ON HETEROATOM CHEMISTRY | 1996年 / 15卷

关键词：

alkyl iodides; cross coupling; dithioacetals; thioethers;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The transition metal-catalyzed cross-coupling reactions of unactivated aliphatic C-X bonds are reviewed. Only simple aliphatic iodides can undergo Suzuki couplings. Nevertheless, specially designed substrates are required for Kumada-Corriu-type cross couplings or the Stille reaction to proceed. Chelation has been demonstrated as a unique tool for activating the otherwise unactivated C-S bonds in the cross-coupling reactions.

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页码：61 / 82

页数：22

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