Acid-functionalized mesoporous carbons for the continuous production of 5-hydroxymethylfurfural

被引：53
作者：
Gallo, Jean Marcel R. [1 ,2 ]
Alamillo, Ricardo [1 ]
Dumesic, James A. [1 ]
机构：
[1] Univ Wisconsin, Dept Chem & Biol Engn, Madison, WI 53706 USA
[2] Univ Fed Sao Carlos, Dept Chem, BR-13560 Sao Carlos, SP, Brazil
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2016年 / 422卷
基金：
美国国家科学基金会;
关键词：
Mesoporous carbon; 5-Hydroxymethylfurfural; Biomass conversion; Heterogeneous catalysis; Deactivation; CARBOHYDRATE DEHYDRATION; FRUCTOSE; CATALYSTS; DEACTIVATION; EFFICIENT; SOLVENTS; SILICA; SYSTEM; WATER;
D O I：
10.1016/j.molcata.2016.01.005
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The stability of solid acid catalysts is essential in the development of sustainable biomass conversion processes. Herein, we study the activity and stability of acid-functionalized periodic mesoporous carbons (CMK-3 and CMK-5) for the continuous production of 5-hydroxymethylfurfural from fructose. The acid-functionalized mesoporous carbon catalysts show comparable selectivities and turnover frequency (TOF) to that of propylsulfonic acid functionalized SBA-15. However, the first-order deactivation rate coefficient of the carbon-based materials are up to 60 times more stable than that for the acid-functionalized SBA 15 catalyst and up to 3 times more stable than commercial Nafion SAC-13. Of the catalysts studied, phenylsulfonic acid CMK-5 showed both the highest TOF for HMF production and lowest deactivation rate coefficient. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：13 / 17
页数：5
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