Heteroferrocene:: The synthesis of bis[(3a,4,5,6,6a-η)-1,3,4,5,6-pentamethylcyclopenta[d]imidazo-2-thionoyl]iron(II)

被引：15

作者：

Arduengo, AJ

Bannenberg, TP

Tapu, D

Marshall, WJ

机构：

[1] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA

[2] DuPont Co Inc, Cent Res & Dev, Expt Stn, Wilmington, DE 19880 USA

来源：

CHEMISTRY LETTERS | 2005年 / 34卷 / 07期

关键词：

D O I：

10.1246/cl.2005.1010

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of bis[(3a,4,5,6,6a-eta)-1,3,4,5,6-pentamethyl-cyclopenta[d]imidazo-2-thionoyl]iron(II) is reported. Structural determination of the unusual hetero-substituted metallocene by X-ray crystallographic analysis is described. Preliminary electrochemical studies reveal that oxidation and reduction potentials for the subject ferrocene lie midway between those of ferrocene and decamethylferrocene.

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页码：1010 / 1011

页数：2

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