Biosorbent derived from coffee husk for efficient removal of toxic heavy metals from wastewater

被引:69
|
作者
Vu Thi Quyen [1 ,2 ]
Thi-Huong Pham [3 ]
Kim, Jitae [4 ]
Dang My Thanh [2 ]
Phan Quang Thang [5 ]
Quyet Van Le [6 ]
Jung, Sung Hoon [3 ]
Kim, TaeYoung [3 ]
机构
[1] Ton Duc Thang Univ, Inst Computat Sci, Div Computat Math & Engn, Ho Chi Minh City, Vietnam
[2] Ton Duc Thang Univ, Fac Environm & Labour Safety, Ho Chi Minh City, Vietnam
[3] Gachon Univ, Dept Mat Sci & Engn, 1342 Seongnam Daero, Seongnam 13120, South Korea
[4] Univ Seoul, Air Pollut Res Ctr, Inst Urban Sci, Seoul, South Korea
[5] Vietnam Acad Sci & Technol VAST, Inst Environm Technol IET, 18 Hoang Quoc Viet, Hanoi, Vietnam
[6] Korea Univ, Dept Mat Sci & Engn, 145 Anam Ro, Seoul 02841, South Korea
基金
新加坡国家研究基金会;
关键词
Coffee husk biomass; Activated biochar; Adsorption; Lead; Cadmium; Wastewater; MODIFIED BIOCHAR; SORPTION; PB(II); IMPROVEMENT; MECHANISMS; CADMIUM; COPPER; NICKEL; LEAD;
D O I
10.1016/j.chemosphere.2021.131312
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In this study, we investigated the feasibility on the utilization of coffee husk as biosorbents for the removal of heavy metal ions such as Pb2+ and Cd2+ from wastewater. Biochar was produced from coffee wastes and modified with sodium hydroxide to create functional groups on the surface and increase the specificic surface area. The resultant products were characterized by using various analytical methods such as scanning electron microscopy, specific area, surface functional group and zeta potential analysis. The as-prepared materials were employed as adsorbent to remove Pb2+ and Cd2+ ions from wastewater. The maximum sorption capacities of biosorbents were measured to be 116.3 and 139.5 mg g(-1) for Cd2+ and Pb2+, respectively, which is comparable to the conventional adsorbents. Kinetic studies showed that the sorption of Pb2+ and Cd2+ on biosorbents can be described by the Freundlich isotherm and second-order kinetic model. The coffee husk-derived biosorbent was capable of removing 89.6% of Pb2+ and 81.5% Cd2+ ions from wastewater, and therefore can be considered as low-cost and efficient adsorbent to remove heavy metal ions from wastewater.
引用
收藏
页数:7
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