A homoleptic thioether coordination sphere that supports nickel(I)

被引：35
作者：
Ge, PH
Riordan, CG
Yap, GPA
Rheingold, AL
机构：
[1] KANSAS STATE UNIV,DEPT CHEM,MANHATTAN,KS 66506
[2] UNIV DELAWARE,NEWARK,DE 19716
来源：
INORGANIC CHEMISTRY | 1996年 / 35卷 / 19期
关键词：
D O I：
10.1021/ic960515k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of diphenylbis((methylthio)methyl)borate (Ph(2)Bt(-)) with Ni(BF4)(2) . 6H(2)O yielded square planar [Ph(2)Bt]Ni-2, 1. Chemical reduction of 1 with Na/Hg produced a species which represents a uniquely stable (NiS4)-S-I chromophore. X-band EPR data: g(1) = 2.27, g(2) = 2.11, g(3) = 2.03.
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页码：5408 / &
页数：3
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