Self-assembly of porous polyaniline microspheres via template-free interfacial method for high-performance electromagnetic absorption property

被引:16
作者
Lei, Yiming [1 ,2 ]
Zhou, Jintang [1 ,2 ]
Yao, Zhengjun [1 ,2 ]
Li, Lin [1 ,2 ]
机构
[1] Nanjing Univ Aeronaut & Astronaut, Coll Mat & Technol, Nanjing 211100, Peoples R China
[2] Nanjing Univ Aeronaut & Astronaut, Minist Ind & Informat Technol, Key Lab Mat Preparat & Protect Harsh Environm Nan, Nanjing 211100, Peoples R China
基金
中国国家自然科学基金;
关键词
Carbon materials; Microstructure; Dielectrics; MICROWAVE-ABSORPTION;
D O I
10.1016/j.matlet.2020.127389
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Self-assembly porous polyaniline (PANI) microspheres were synthesized via template-free interfacial method at the interface of gallic acid aqueous solution and carbon tetrachloride. The morphology of PANI can be controlled by changing the content of gallic acid. The obtained porous PANI microspheres showed good electromagnetic (EM) wave absorption performance. The maximum reflection loss value of which is -26.5 dB and the effective absorption bandwidth (reflection loss <-10 dB) is about 4.1 GHz. This study is mainly focused on analyzing EM loss based on complex permittivity as the magnetic loss of PANI is neglectable. Further EM analysis indicated that porous PANI microspheres have better impedance matching and attenuation constant, which attributes to the good EM wave absorption. This work can act as a reference for designing PANI microspheres as EM wave absorber by the template-free process. (C) 2020 Published by Elsevier B.V.
引用
收藏
页数:5
相关论文
共 11 条
  • [1] Urchin-like polyaniline microspheres fabricated from self-assembly of polyaniline nanowires and their electro-responsive characteristics
    Kim, Min Ji
    Liu, Ying Dan
    Choi, Hyoung Jin
    [J]. CHEMICAL ENGINEERING JOURNAL, 2014, 235 : 186 - 190
  • [2] Synthesis and high-performance microwave absorption of reduced graphene oxide/Co-doped ZnNi ferrite/polyaniline composites
    Lei, Yiming
    Yao, Zhengjun
    Lin, Haiyan
    Haidry, Azhar Ali
    Zhou, Jintang
    Liu, Peijiang
    [J]. MATERIALS LETTERS, 2019, 236 : 456 - 459
  • [3] Chiral polyaniline with superhelical structures for enhancement in microwave absorption
    Li, Xiang
    Yu, Lujun
    Yu, Laiming
    Dong, Yubing
    Gao, Qiang
    Yang, Qixin
    Yang, Wentong
    Zhu, Yaofeng
    Fu, Yaqin
    [J]. CHEMICAL ENGINEERING JOURNAL, 2018, 352 : 745 - 755
  • [4] Small magnetic Co-doped NiZn ferrite/graphene nanocomposites and their dual-region microwave absorption performance
    Liu, Peijiang
    Yao, Zhengjun
    Zhou, Jintang
    Yang, Zhihong
    Kong, Ling Bing
    [J]. JOURNAL OF MATERIALS CHEMISTRY C, 2016, 4 (41) : 9738 - 9749
  • [5] Template-free synthesis and characterization of single-phase voided poly(o-anisidine) and polyaniline colloidal spheres
    Tan, Yiwei
    Bai, Feng
    Wang, Dingsheng
    Peng, Qing
    Wang, Xun
    Li, Yadong
    [J]. CHEMISTRY OF MATERIALS, 2007, 19 (23) : 5773 - 5778
  • [6] Morphological control of self-assembly polyaniline micro/nano-structures using dichloroacetic acid
    Wang, Hongjuan
    Lu, Yun
    [J]. SYNTHETIC METALS, 2012, 162 (15-16) : 1369 - 1374
  • [7] Interface Modulating CNTs@PANi Hybrids by Controlled Unzipping of the Walls of CNTs To Achieve Tunable High-Performance Microwave Absorption
    Wang, Huagao
    Meng, Fanbin
    Huang, Fei
    Jing, Changfei
    Li, Ying
    Wei, Wei
    Zhou, Zuowan
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2019, 11 (12) : 12142 - 12153
  • [8] Enhanced microwave absorption performances of polyaniline/graphene aerogel by covalent bonding
    Wang, Yan
    Gao, Xiang
    Fu, Yuqiao
    Wu, Xinming
    Wang, Qiguan
    Zhang, Wenzhi
    Luo, Chunyan
    [J]. COMPOSITES PART B-ENGINEERING, 2019, 169 : 221 - 228
  • [9] Wei ZX, 2002, ADV MATER, V14, P1314, DOI 10.1002/1521-4095(20020916)14:18<1314::AID-ADMA1314>3.0.CO
  • [10] 2-9