The 4s-and 4p-XPS spectra of Xe, XeF2 and XeF4

被引：3

作者：

Ohno, M ^{[1
]}

机构：

[1] Quantum Sci Res, Itabashi Ku, Tokyo 1740071, Japan

来源：

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 2003年 / 130卷 / 1-3期

关键词：

4s-and 4pXPS spectra; Xe; XeF2; XeF4; ab-initio atomic many body theory; chemical shift;

D O I：

10.1016/S0368-2048(03)00019-7

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The 4s- and 4p- XPS spectra of Xe gas, XeF2 molecule and XeF4 molecule are calculated by an ab-initio atomic many-body theory. The 4s-peak and the prominent '4p'-peak are predicted well by the present theory. In XeF2 and XeF4 the spectral lines observed below the 4d-double ionization threshold are the 4d(-2)4f multiplet states strongly perturbed by the interaction with the initial 4p(1/2)-hole state. They are very similar to the spectral lines which emerge with an increase in atomic number (e.g. Ba). (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：19 / 24

页数：6

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