The 4s-and 4p-XPS spectra of Xe, XeF2 and XeF4

被引：3
|
作者：
Ohno, M [1 ]
机构：
[1] Quantum Sci Res, Itabashi Ku, Tokyo 1740071, Japan
来源：
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 2003年 / 130卷 / 1-3期
关键词：
4s-and 4pXPS spectra; Xe; XeF2; XeF4; ab-initio atomic many body theory; chemical shift;
D O I：
10.1016/S0368-2048(03)00019-7
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
The 4s- and 4p- XPS spectra of Xe gas, XeF2 molecule and XeF4 molecule are calculated by an ab-initio atomic many-body theory. The 4s-peak and the prominent '4p'-peak are predicted well by the present theory. In XeF2 and XeF4 the spectral lines observed below the 4d-double ionization threshold are the 4d(-2)4f multiplet states strongly perturbed by the interaction with the initial 4p(1/2)-hole state. They are very similar to the spectral lines which emerge with an increase in atomic number (e.g. Ba). (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：19 / 24
页数：6
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