Synthetic Polymers from Readily Available Monosaccharides

被引:42
作者
Galbis, J. A. [1 ]
Garcia-Martin, M. G. [1 ]
机构
[1] Univ Seville, Fac Farm, Dept Quim Organ & Farmaceut, Seville 41071, Spain
来源
CARBOHYDRATES IN SUSTAINABLE DEVELOPMENT II: A MINE FOR FUNCTIONAL MOLECULES AND MATERIALS | 2010年 / 295卷
关键词
alpha; omega-Alkanediamines; 1,4:3,6-Dianhydrohexitols; Aldaric acids; Aldonolactones; Aminoalditols; D-Glucitol; Diaminoalditols; D-Mannitol; D-Xylitol application; Erythritols; Isoidide; Isomannide; Isosorbide; L-Arabinitol; Lipase-catalysis; Polyamides; Polycarbonates; Polyesteramides; Polyesters; Polyethers; Polyureas; Polyurethanes; Super-acid; Tartaric acids; D-GLUCARIC ACID; RING-OPENING POLYMERIZATION; CARBOHYDRATE-BASED MONOMERS; RENEWABLE RESOURCES; HYDROLYTIC DEGRADATION; LINEAR POLYURETHANES; CARBONIC-ACID; L-ARABINITOL; HYDROXYLATED NYLON-6; ALDARIC ACIDS;
D O I
10.1007/128_2010_57
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The low degradability of petroleum-based polymers and the massive use of these materials constitute a serious problem because of the environmental pollution that they can cause. Thus, sustained efforts have been extensively devoted to produce new polymers based on natural renewing resources and with higher degradability. Of the different natural sources, carbohydrates stand out as highly convenient raw materials because they are inexpensive, readily available, and provide great stereochemical diversity. New polymers, analogous to the more accredited technical polymers, but based on chiral monomers, have been synthesized from natural and available sugars. This chapter describes the potential of sugar-based monomers as precursors to a wide variety of macromolecular materials.
引用
收藏
页码:147 / 176
页数:30
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