Textural properties of activated carbons from apricot stones

被引:33
|
作者
Youssef, AM
Radwan, NRE [1 ]
Abdel-Gawad, I
Singer, GAA
机构
[1] Suez Canal Univ, Fac Educ, Dept Chem, Suez 1262, Egypt
[2] Mansoura Univ, Fac Sci, Dept Chem, Mansoura, Egypt
[3] Nasr Petr Co, Suez, Egypt
关键词
apricot stones; activated carbon; phosphoric acid; zinc chloride; steam activation;
D O I
10.1016/j.colsurfa.2004.09.008
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Chemically activated carbons were prepared from apricot stones. Phosphoric acid (25-75 wt.%) was used as an activating agent at 400-600degreesC. Zinc chloride-activated carbon were also prepared at 600 and 700degreesC using three different zinc chloride: apricot stone ratios of 0.5, 1.0 and 2.0. Steam-activated carbons were obtained by gasifying un-activated carbon obtained by carbonizing apricot stones, at 900degreesC to burn-off 25 and 35 %. The textural parameters were determined from the nitrogen adsorption data at 77 K. Different adsorption models were considered for the analysis of the adsorption results. Considerable differences between surface areas and pore volume as obtained by considering the different models, have been observed. However, the method of analysis based on comparing the isotherm determined for a given active carbon with the standard isotherm for a non-porous adsorbent seems to be trustworthy. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:143 / 151
页数:9
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