Thermodynamic modelling of the O-Sn system

被引：70
|
作者：
Cahen, S [1 ]
David, N [1 ]
Fiorani, JM [1 ]
Maître, A [1 ]
Vilasi, M [1 ]
机构：
[1] Univ Nancy 1, Lab Chim Solide Mineral, Thermodynam & Corros Grp, CNRS,UMR 7555, F-54506 Vandoeuvre Les Nancy, France
来源：
THERMOCHIMICA ACTA | 2003年 / 403卷 / 02期
关键词：
thermodynamic modelling; O-Sn system; DSC and XRD experiments; ionic liquid model;
D O I：
10.1016/S0040-6031(03)00059-5
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Thermodynamic and phase diagram data relative to the O-Sn system have been assessed. The existence, the type and the temperature of invariant equilibria Melt1((l)) reversible arrow Melt2((l)) + SnO2(s) and Sn3O4(s) reversible arrow 2SnO((s)) + SnO2(s) have been the subject of DSC and XRD experiments. The adjustable parameters of the modelling are obtained by the CALculation of PHAse Diagram (CALPHAD) method fitted thanks to diagram and thermodynamic data through Thermo-Calc(TM) software. In particular, the liquid phase is described by the way of the Hillert's partially ionic liquid model. The final result is in good agreement with all of the experimental data available. Activities of tin and oxygen versus composition at different high temperatures can be calculated. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码：275 / 285
页数：11
相关论文
共 50 条
  • [21] Thermodynamic re-modelling of the Cu-Nb-Sn system: Integrating the nausite phase
    Lachmann, Jonas
    Kriegel, Mario J.
    Leineweber, Andreas
    Shang, Shun-Li
    Liu, Zi-Kui
    CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 2022, 77
  • [22] Thermodynamic description of the Cu–Sn system
    Wojcieh Gierlotka
    Sinn-wen Chen
    Shih-kang Lin
    Journal of Materials Research, 2007, 22 : 3158 - 3165
  • [23] Thermodynamic optimization of the Ho–Sn system
    A. Iddaoudi
    N. Selhaoui
    S. Kardellass
    M. Ait Amar
    K. Mahdouk
    H. Najih
    L. Bouirden
    Journal of Thermal Analysis and Calorimetry, 2014, 115 : 941 - 945
  • [24] Thermodynamic optimization of the (In,Sn) binary system
    El Aissaoui, K
    Selhaoui, N
    Bouirden, L
    Hertz, J
    REVUE DE METALLURGIE-CAHIERS D INFORMATIONS TECHNIQUES, 2004, 101 (09): : 723 - +
  • [25] Thermodynamic Assessment of the Sn–Ti System
    Chunlei Liu
    Ulrich E. Klotz
    Peter J. Uggowitzer
    Jörg F. Löffler
    Monatshefte für Chemie / Chemical Monthly, 2005, 136 : 1921 - 1930
  • [26] Thermodynamic optimization of the Yb–Sn system
    Mohamed Idbenali
    Colette Servant
    Journal of Thermal Analysis and Calorimetry, 2011, 103 : 131 - 135
  • [27] THE TERNARY-SYSTEM SN-TA-O - PHASE STABILITIES AND THERMODYNAMIC BEHAVIOR
    BIEGER, W
    KRABBES, G
    RITSCHEL, M
    WIESNER, U
    EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY, 1991, 28 (05): : 999 - 1009
  • [28] Thermodynamic properties and thermodynamic assessment of Ta-Sn system
    Wang Jianli
    Tuo Biyang
    Hu Xunpu
    Liu Zhulin
    ADVANCES IN TEXTILE ENGINEERING AND MATERIALS III, PTS 1 AND 2, 2013, 821-822 : 849 - +
  • [29] Thermodynamic modelling of phase equilibria in the quaternary system Bi/Te/Se/O
    Schmidt, P
    Oppermann, H
    HIGH TEMPERATURE MATERIALS CHEMISTRY, PTS I AND II, PROCEEDINGS, 2000, 15 : 53 - 57
  • [30] Phase relation assessment of the O-Pu-Zr system by thermodynamic modelling
    Kinoshita, H
    Uno, M
    Yamanaka, S
    JOURNAL OF ALLOYS AND COMPOUNDS, 2003, 354 (1-2) : 129 - 137
12345