Excess volumes and excess heat capacities of nitromethane plus (1-propanol or 2-propanol)

被引：49
|
作者：
Cerdeiriña, CA [1 ]
Tovar, CA [1 ]
Troncoso, J [1 ]
Carballo, E [1 ]
Romaní, L [1 ]
机构：
[1] Univ Vigo, Fac Ciencias, Dept Fis Aplicada, E-32004 Orense, Spain
来源：
FLUID PHASE EQUILIBRIA | 1999年 / 157卷 / 01期
关键词：
experimental; excess functions; specific interactions;
D O I：
10.1016/S0378-3812(99)00018-7
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Densities and heat capacities of binary mixtures containing nitromethane + (1-propanol or 2-propanol) were determined at the temperatures (288.15, 293.15, 298.15, and 308.15) K and atmospheric pressure, over the whole composition range. Excess molar volumes and excess molar isobaric heat capacities were calculated from the results thus obtained. The effect of specific interactions on the excess properties, and the dependence on the position of the OH group in the alkanol, are analysed. (C) 1999 Elsevier Science B.V. All rights reserved.
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页码：93 / 102
页数：10
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