Carrier Conduction Characteristics in P3HT: PCBM Bulk Heterojunction Structures Under Sunlight Illumination

被引：0

作者：

Lou, Yanhui ^{[1
]}

Wang, Zhaokui ^{[1
]}

Naka, Shigeki ^{[1
]}

Okada, Hiroyuki ^{[1
]}

机构：

[1] Toyama Univ, Grad Sch Sci & Technol, Toyama 9308555, Japan

来源：

9TH INTERNATIONAL CONFERENCE ON NANO-MOLECULAR ELECTRONICS | 2011年 / 14卷

关键词：

Organic Solar Cells; Bulk heterojunction; Carrier injection; POLYMER SOLAR-CELLS; PHOTOVOLTAIC CELLS; EFFICIENCY; MORPHOLOGY; NETWORK;

D O I：

10.1016/j.phpro.2011.05.041

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Injection properties of electrons and holes at the interface of electrodes/active layer for blending poly(3-hexylthiophene) (P3HT) and methanofullerene [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) based on structures of Au/MoO3/P3HT: PCBM/MoO3/Au as hole dominated device and Al alloy/P3HT: PCBM/Al alloy as electron dominated device were investigated. Both of hole and electron injections were ascribed to Schottky thermionic emission mechanism. The barrier height of carrier injection was estimated under a simulated air mass (AM) 1.5G spectrum illumination and dark conditions, respectively. The interfacial state at Al alloys/P3HT: PCBM interface was estimated to be 1.4 x 10(14) states/cm(2)/eV under illumination by extrapolating the relation of electron barrier heights and work functions using different Al alloys. (C) 2010 Published by Elsevier B.V.

引用

页数：5

共 18 条

[1]

Alsema EA, 2000, PROG PHOTOVOLTAICS, V8, P17, DOI 10.1002/(SICI)1099-159X(200001/02)8:1<17::AID-PIP295>3.0.CO

[2]

2-C

[3] Polymer solar cells with enhanced open-circuit voltage and efficiency [J].

Chen, Hsiang-Yu ;

Hou, Jianhui ;

Zhang, Shaoqing ;

Liang, Yongye ;

Yang, Guanwen ;

Yang, Yang ;

Yu, Luping ;

Wu, Yue ;

Li, Gang .

NATURE PHOTONICS, 2009, 3 (11) :649-653

[4] Recent Progress in Polymer Solar Cells: Manipulation of Polymer: Fullerene Morphology and the Formation of Efficient Inverted Polymer Solar Cells [J].

Chen, Li-Min ;

Hong, Ziruo ;

Li, Gang ;

Yang, Yang .

ADVANCED MATERIALS, 2009, 21 (14-15) :1434-1449

[5] Polymer-Fullerene Bulk-Heterojunction Solar Cells [J].

Dennler, Gilles ;

Scharber, Markus C. ;

Brabec, Christoph J. .

ADVANCED MATERIALS, 2009, 21 (13) :1323-1338

[6]

GREEN MA, 2000, 3 GENERATION PHOTOVO

[7] Using self-assembling dipole molecules to improve charge collection in molecular solar cells [J].

Khodabakhsh, S ;

Sanderson, BM ;

Nelson, J ;

Jones, TS .

ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (01) :95-100

[8] Efficient tandem polymer solar cells fabricated by all-solution processing [J].

Kim, Jin Young ;

Lee, Kwanghee ;

Coates, Nelson E. ;

Moses, Daniel ;

Nguyen, Thuc-Quyen ;

Dante, Mark ;

Heeger, Alan J. .

SCIENCE, 2007, 317 (5835) :222-225

[9] New architecture for high-efficiency polymer photovoltaic cells using solution-based titanium oxide as an optical spacer [J].

Kim, JY ;

Kim, SH ;

Lee, HH ;

Lee, K ;

Ma, WL ;

Gong, X ;

Heeger, AJ .

ADVANCED MATERIALS, 2006, 18 (05) :572-+

[10] For the Bright Future-Bulk Heterojunction Polymer Solar Cells with Power Conversion Efficiency of 7.4% [J].

Liang, Yongye ;

Xu, Zheng ;

Xia, Jiangbin ;

Tsai, Szu-Ting ;

Wu, Yue ;

Li, Gang ;

Ray, Claire ;

Yu, Luping .

ADVANCED MATERIALS, 2010, 22 (20) :E135-+

← 1 2 →