Selective Hydrogenation of Nitrile-Butadiene Rubber Catalyzed by Thermoregulated Phase Transfer Phosphine Rhodium Complex

被引:19
作者
Ning, Simin [1 ,2 ]
Yang, Shoufa [1 ,2 ]
Wei, Xinpeng [1 ,2 ]
Wang, Weimin [3 ]
Zhang, Liqun [1 ,2 ]
Yue, Dongmei [1 ,2 ]
机构
[1] Beijing Univ Chem Technol, Minist Educ, Key Lab Carbon Fiber & Funct Polymers, Beijing 100029, Peoples R China
[2] Beijing Univ Chem Technol, Key Lab Preparat & Proc Novel Polymer Mat, Beijing 100029, Peoples R China
[3] Abon Pharmaceut LLC, Weimin Wang, Northvale, NJ 07647 USA
基金
中国国家自然科学基金;
关键词
metal-polymer complex; metal-organic catalysts; catalysts; rubber; selectivity; TRANSFER LIGANDS; 2-PHASE HYDROFORMYLATION; BIPHASIC SYSTEM; COPOLYMERS; POLYMERS; 1-DECENE; OLEFINS; WATER;
D O I
10.1002/app.34558
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Hydrogenation of polymer having C C double bond can be carried out with the metal-organic complex as catalyst, which has the property of themoregulated phase transfer. In this study, a new complex RhCl[PPh[(OCH(2)CH(2))(5 <= n <= 6)CH(3)](2)](3) (Rh/AEOPP) was synthesized with a good yield, which was further used as catalyst to selectively hydrogenated nitrile-butadiene rubber (HNBR). This is the first time that Rh/AEOPP complex was synthesized and applied in nitrile-butadiene rubber (NBR) hydrogenation. The result shows that hydrogenation degree of product (HNBR) can be extended to 90%, when the condition is [Cat] = 3% (based the weight of NBR), L(2): Cat (Weight Ratio) = 2, [NBR] = 5% (based on the weight of xylene solution), P (H(2)) = 1.5 MPa, T = 155 degrees C, and t = 8 h. Also, by adjusting temperature, the catalyst could be easily separated from products with 89% catalyst complex recovery. In addition, (1)H-NMR and infrared (IR) spectra showed that C=C double bonds in NBR was successfully hydrogenated without causing reduction of the CN group. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 123: 1040-1046, 2012
引用
收藏
页码:1040 / 1046
页数:7
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