The Use of an Organoclay on the Compatibilization of PP/EPDM Blends

被引:10
作者
Ferreira, Kaline R. M. [2 ]
Leite, Itamara F. [3 ]
Siqueira, Alex da S.
Raposo, Claudia M. O. [4 ]
Carvalho, Laura H. [1 ]
Silva, Suedina M. L. [1 ]
机构
[1] Univ Fed Campina Grande, Unidade Acad Engn Mat, BR-58429140 Campina Grande, PB, Brazil
[2] Univ Fed Campina Grande, Programa Posgrad Ciencia & Engn Mat, BR-58429140 Campina Grande, PB, Brazil
[3] Univ Fed Paraiba, Dept Mat Engn, Joao Pessoa, Paraiba, Brazil
[4] Univ Fed Campina Grande, Unidade Acad Mineracao & Geol, BR-58429140 Campina Grande, PB, Brazil
来源
POLIMEROS-CIENCIA E TECNOLOGIA | 2011年 / 21卷 / 05期
关键词
PP/EPDM blends; organoclay; compatibilization; MODIFIED LAYERED SILICATE; TPO BASED NANOCOMPOSITES; RHEOLOGICAL PROPERTIES; POLYPROPYLENE; MORPHOLOGY; CLAY; EFFICIENCY; STRENGTH; RATIO;
D O I
10.1590/S0104-14282011005000072
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
PP/EPDM blends with different PP:EPDM ratios, non-compatibilized and compatibilized with maleic anhydride grafted polypropylene (PP-g-MA) were prepared by melting. The influence of 1 phr bentonite clay addition on the morphology, mechanical and rheological properties of these blends was evaluated. The bentonite used as a filler, provided by Bentonit Uniao Nordeste/PB, was purified and organically modified with a technology developed by our research group, before being added to the blends. X-ray diffraction results showed that, for blends having different PP:EPDM ratios, 1 phr organoelay addition led to the formation of intercalated (20 or 40% EPDM) or intercalated/exfoliated (10 and 30% EPDM) nanocomposites. The morphological, mechanical and rheological properties of the blends were modified by organoclay addition, especially for those with 30 wt% of EPDM, where a compatibilizing effect of the organoclay was observed.
引用
收藏
页码:421 / 428
页数:8
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