Self-assembly Behavior of Aryl Amide Nucleating Agent under Supercritical Carbon dioxide and its Influence on Polypropylene

被引:18
作者
Li, Zhengkun [1 ]
Liu, Yuansen [2 ]
Nie, Min [1 ]
Wang, Qi [1 ]
机构
[1] Sichuan Univ, State Key Lab Polymer Mat Engn, Polymer Res Inst, Chengdu 610065, Sichuan, Peoples R China
[2] State Ocean Adm, Inst Oceanog 3, Engn Res Ctr Marine Biol Resource Comprehens Util, Xiamen, Peoples R China
基金
中国国家自然科学基金;
关键词
-nucleating agent; modification; polypropylene; self-assembly; supercritical carbon dioxide; HYBRID SHISH-KEBAB; ISOTACTIC POLYPROPYLENE; MECHANICAL-PROPERTIES; CRYSTALLINE MORPHOLOGY; CO2; SOLUBILITY; POLYMERS;
D O I
10.1080/03602559.2017.1298792
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Supercritical carbon dioxide-assisted extrusion was adopted to prepare polypropylene containing aryl amide nucleating agent. The experimental results showed that supercritical carbon dioxide did not affect the nucleating efficiency of nucleating agent on polypropylene but acted as a carrier to facilitate the dissolution and self-assembly in polymer melts, so as to promote polypropylene crystallize into rich -modification of needle-like crystals with outstanding toughening effect at low temperature.
引用
收藏
页码:1937 / 1941
页数:5
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