P(C6H4CH2NMe2-2)3-stabilized mononuclear pentafluoropropionatosilver(I)

被引：3
|
作者：
Shen, YZ
Pritzkow, H
Walfort, B
Rüffer, T
Lang, H
机构：
[1] Tech Univ Chemnitz, Fak Nat Wissensch, Inst Chem, Lehrstuhl Anorgan Chem, D-09111 Chemnitz, Germany
[2] Univ Heidelberg, Inst Anorgan Chem, D-69120 Heidelberg, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2004年 / 60卷
关键词：
D O I：
10.1107/S1600536803028320
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title complex, (pentafluoropropionato){tris[2-(dimethylaminomethyl)phenyl]phosphine}silver(I), [P(C6H4CH2NMe2-2)(3)]Ag[OC(O)CF2CF3] or [Ag(C3F5O2)(C27H36N3P)], possesses a tetracoordinated silver(I) ion, with silver in a distorted tetrahedral environment. In the solid state, two independent molecules are found in the asymmetric unit. The P(C6H4CH2NMe2-2)(3) group acts as a tripodal ligand.
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收藏
页码：M91 / M93
页数：3
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