Supramolecular frameworks composed of Ru(II), Cu(II), Zn(II), Ni(II) and Fe(II) complexes having tridentate 4′-chloro-2,2′: 6′ 2"-terpyridine ligand and 1:1 or 1:2 ratios of metal and ligand

被引：28
|
作者：
Huang, Wei [1 ]
Qian, Huifen [2 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Nanjing Univ Technol, Coll Sci, Nanjing 210009, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2008年 / 874卷 / 1-3期
基金：
中国国家自然科学基金;
关键词：
4 '-chloro-2,2 ': 6 ',2 ''-terpyridine; transition metal complexes; hydrogen bonding interactions; supramolecular networks;
D O I：
10.1016/j.molstruc.2007.03.038
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Syntheses, molecular and crystal structures of Ru(II), Cu(II) and Zn(II) 1:1 complexes and Ni(II) and Fe(II) 1:2 complexes of 4-chloro2,2':6',2 ''-terpyridine (L), formulated as trans-[Ru(L-kappa N-3,N',N '')(DMSO-kappa S)Cl-2]center dot 2H(2)O (1), trans-[Cu(L-kappa(3) N,N',N '')(ClO4-kappa O)(2)(H2O-kappa O)] (2) and (Zn(L-kappa N-3,N',N '' cl(2)] (3), [Ni(L-kappa N-3,N',N '')(2)]Cl-2 center dot 3H(2)O (4), [Ni(L-kappa N-3,N',N '')(2)](BF4)(2) (5), and [Fe(L-kappa(3) N,N',N '')(2)]Cl-2 center dot 4H(2)O (6) were described in this paper. Versatile interactions in supramolecular level including coordinative bonding, O-H center dot center dot center dot O, O-H center dot center dot center dot Cl, C-H center dot center dot center dot O and C-H center dot center dot center dot Cl hydrogen bonding, pi-pi stacking play essential roles in forming different frameworks of 1-6. (c) 2007 Elsevier B.V. All rights reserved.
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收藏
页码：64 / 76
页数：13
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