N2,N2′-Bis(2,2-dimethylpropanoyl)-benzene-1,3-dicarbohydrazide

被引:8
|
作者
Fun, Hoong-Kun [1 ]
Chantrapromma, Suchada [2 ]
Jana, Subrata [3 ]
Hazra, Anita [3 ]
Goswami, Shyamaprosad [3 ]
机构
[1] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia
[2] Prince Songkla Univ, Fac Sci, Dept Chem, Hat Yai 90112, Songkhla, Thailand
[3] Bengal Engn & Sci Univ, Dept Chem, Sibpur 711103, Howrah, India
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词
D O I
10.1107/S1600536807063210
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the molecular structure of the title hydrazide derivative, C18H26N4O4, the conformations of the two units of 2-(2,2-dimethyl-1-oxopropyl) hydrazide substituents are not planar; these two units are attached axially to the benzene ring with C(ortho)-C-C(=O)-N torsion angles of 28.1 (2) and 31.0 (2)degrees [where C(ortho) is the C atom at position 4 of the benzene ring relative to the substituent at position 3 or the C atom at position 6 of the benzene ring relative to the substituent at position 1, as appropriate]. The dihedral angles between the hydrazide units and the benzene ring are 62.66 (7) and 63.84 (7)degrees. In the crystal structure, molecules are arranged in an anti-parallel manner and are linked by N-H center dot center dot center dot O intermolecular hydrogen bonds and weak C-H center dot center dot center dot O intermolecular interactions into a three-dimensional network. The structure is further stabilized by a weak C-H center dot center dot center dot N intramolecular interaction.
引用
收藏
页码:O175 / U4082
页数:12
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