Transition metal-induced B-H functionalization of o-carborane

被引：163

作者：

Zhang, Xiaolei ^{[1
,2
]}

Yan, Hong ^{[1
]}

机构：

[1] Nanjing Univ, Jiangsu Key Lab Adv Organ Mat, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210023, Jiangsu, Peoples R China

[2] Jiangnan Univ, Sch Pharmaceut Sci, Wuxi 214122, Jiangsu, Peoples R China

来源：

COORDINATION CHEMISTRY REVIEWS | 2019年 / 378卷

关键词：

B-H functionalization; Carborane; Half-sandwich complex; Mechanism; HALF-SANDWICH COMPLEXES; CP-ASTERISK-RH; CHELATING 1,2-DICARBA-CLOSO-DODECABORANE-1,2-DICHALCOGENOLATE LIGAND; O-CARBORANE-1,2-DITHIOLATE LIGAND; HALFSANDWICH COMPLEXES; POLYHEDRAL BORANES; CRYSTAL-STRUCTURE; 16-ELECTRON CPCO; ACTIVATION; BORON;

D O I：

10.1016/j.ccr.2017.11.006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Transition metal-mediated B-H functionalization of carboranes has drawn increasing interests during the last two decades. This review describes how to incorporate B-H functionalization into the derivation of half-sandwich transition metal complexes containing o-carborane dichalcogenolates. The detailed mechanistic elucidations for metal-induced versatile B-H functionalization are also reviewed. Examples of selective B-H activation, stepwise B-H functionalization, cobalt-mediated B-H functionalization as well as dimetal-mediated B-H activation of o-carborane are discussed. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：466 / 482

页数：17

共 91 条

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