Controllable Synthesis of Metal-Organic Frameworks: From MOF Nanorods to Oriented MOF Membranes

被引：378

作者：

Li, Yan-Shuo ^{[1
,2
,3
]}

Bux, Helge ^{[1
,2
]}

Feldhoff, Armin ^{[1
,2
]}

Li, Guo-Ling ^{[3
]}

Yang, Wei-Shen ^{[3
]}

Caro, Juergen ^{[1
,2
]}

机构：

[1] Leibniz Univ Hannover, Inst Phys Chem & Electrochem, D-30167 Hannover, Germany

[2] Leibniz Univ Hannover, Ctr Solid State Res & New Mat, LNQE, D-30167 Hannover, Germany

[3] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

来源：

ADVANCED MATERIALS | 2010年 / 22卷 / 30期

关键词：

MOLECULAR-SIEVE MEMBRANE; THIN-FILMS; GROWTH; CU-3(BTC)(2); RESISTANCES;

D O I：

10.1002/adma.201000857

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tailoring of the crystal size and morphology of metal-organic framework (MOF) materials and manipulation of MOF films is possible by the solvothermal synthesis route introduced here. A c-out-of-plane ZIF-7 membrane (see figure) is obtained through evolutionary selection in a van der Drift-type growth originating from randomly oriented seed layers. Highly oriented MOF thin films are important as molecular sieve membranes.

引用

页码：3322 / +

页数：6

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