Three-dimensional lanthanoid-containing coordination frameworks: Structure, magnetic and fluorescent properties

被引：39

作者：

Zhang, HT

Song, Y

Li, YX

Zuo, JL

Gao, S

You, XZ ^{[1
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2005年 / Wiley-VCH Verlag卷 / 04期

关键词：

lanthanides; coordination polymers; magnetic properties; fluorescence; solid-state structures;

D O I：

10.1002/ejic.200400376

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two lanthanoid-containing 3D coordination polymers, [Gd2L3(H2O)(2)](n) (1) and {[TbL1.5(H2O)](.)0.5H(2)O}(n) (2) (L = succinate), have been prepared by hydrothermal reaction. The difference in structure between the two 3D coordination polymers is a result of the flexibility of the ligand conformation. The magnetic properties of I and 2 have been investigated in the 1.8-300 K range. Both complexes exhibit ferromagnetic interaction between lanthanoid ions. AC magnetic measurements revealed long-range magnetic order in complex 2. Especially 2 integrates the ferromagnetic, fluorescent and porous properties into a single entity. This motif may be developed to achieve new multifunctional molecular-based materials. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005.

引用

页码：766 / 772

页数：7

共 62 条

[1] Structural characterisation, EPR and magnetic properties of f-f and f-d lanthanide(III) phenolic cryptates [J].