Fracture toughness and impact strength of anhydride-cured biobased epoxy

被引:143
作者
Miyagawa, H
Misra, M
Drzal, LT
Mohanty, AK
机构
[1] Michigan State Univ, Ctr Composite Mat & Struct, E Lansing, MI 48824 USA
[2] Michigan State Univ, Sch Packaging, E Lansing, MI 48824 USA
关键词
D O I
10.1002/pen.20290
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Biobased neat epoxy materials containing functionalized vegetable oils (FVO), such as epoxidized linseed oil (ELO) and epoxidized soybean oil (ESO), were processed with an anhydride curing agent. A percentage of diglycidyl ether of bisphenol F (DGEBF) was replaced by ELO or ESO. The selection of the DGEBF, FVO, and an anhydride-curing agent resulted in an excellent combination to produce a new biobased epoxy material having a high elastic modulus and high glass transition temperature. Izod impact strength and fracture toughness were significantly improved dependent on FVO content, which produced a phase-separated morphology. (c) 2005 Society of Plastics Engineers.
引用
收藏
页码:487 / 495
页数:9
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